Examining all shelf number combinations with the given energy and
then picking out the combination that has the most energy
eigenfunctions seems straightforward enough, but it runs into a
problem. The problem arises when it is required that the set of
shelf numbers agrees with the given energy to mathematical precision.
To see the problem, recall the simple model system of chapter
11.3 that had only three energy shelves. Now assume that
the energy of the second shelf is not
as assumed there,
(still arbitrary units), but slightly less at
. The
difference is small, and all figures of chapter 11.3 are
essentially unchanged. However, if the average energy per particle is
still assumed equal to 2.5, so that the total system energy equals the
number of particles
times that amount, then
must be zero: it
is impossible to take a nonzero multiple of an irrational number like
and end up with a rational number like
.
What this means graphically is that the oblique energy line in the
equivalent of figure 11.5 does not hit any of the centers
of the squares mathematically exactly, except for the one at
.
So the conclusion would be that the system must have zero particles on
the middle shelf.
Of course, physically this is absolute nonsense; the energy of a large
number of perturbed particles is not going to be certain to be 2.5
to mathematical precision. There will be some uncertainty in
energy, and the correct shelf numbers are still those of the darkest
square, even if its energy is 2.499,9...
instead of 2.5
exactly. Here typical textbooks will pontificate about the accuracy
of your system-energy measurement device. However, this book shudders
to contemplate what happens physically in your glass of ice water if
you have three system-energy measurement devices, but your best one is
in the shop, and you are uncertain whether to believe the unit you got
for cheap at Wal-Mart or your backup unit with the sticking needle.
To avoid these conundrums, in this book it will simply be assumed that
the right combination of shelf occupation numbers is still the one at
the maximum in figure 11.6, i.e. the maximum when the
number of energy eigenfunctions is mathematically interpolated by a
continuous function. Sure, that may mean that the occupation numbers
are no longer exact integers. But who is going to count ![]()
If fractional particles bothers you, even among ![]()